Ozone Depletion

The Earth's ozone layer protects all life from the sun's harmful radiation, but human activities have damaged this shield. Less protection from ultraviolet light will, over time, lead to higher skin cancer and cataract rates and crop damage. The U.S., in cooperation with over 140 other countries, is phasing out the production of ozone-depleting substances in an effort to safeguard the ozone layer.

The Earth's atmosphere is divided into several layers. The lowest region, the troposphere, extends from the Earth's surface up to about 10 kilometers (km) in altitude. Virtually all human activities occur in the troposphere. Mt. Everest, the tallest mountain on the planet, is only about 9 km high. The next layer, the stratosphere, continues from 10 km to about 50 km. Most commercial airline traffic occurs in the lower part of the stratosphere.

Most atmospheric ozone is concentrated in a layer in the stratosphere, about 15-30 kilometers above the Earth's surface. Ozone is a molecule containing three oxygen atoms. It is blue in color and has a strong odor. Normal oxygen, which we breathe, has two oxygen atoms and is colorless and odorless. Ozone is much less common than normal oxygen. Out of each 10 million air molecules, about 2 million are normal oxygen, but only 3 are ozone.

However, even the small amount of ozone plays a key role in the atmosphere. The ozone layer absorbs a portion of the radiation from the sun, preventing it from reaching the planet's surface. Most importantly, it absorbs the portion of ultraviolet light called UVB. UVB has been linked to many harmful effects, including various types of skin cancer, cataracts, and harm to some crops, certain materials, and some forms of marine life.

At any given time, ozone molecules are constantly formed and destroyed in the stratosphere. The total amount, however, remains relatively stable. The concentration of the ozone layer can be thought of as a stream's depth at a particular location. Although water is constantly flowing in and out, the depth remains constant.

While ozone concentrations vary naturally with sunspots, the seasons, and latitude, these processes are well understood and predictable. Scientists have established records spanning several decades that detail normal ozone levels during these natural cycles. Each natural reduction in ozone levels has been followed by a recovery. Recently, however, convincing scientific evidence has shown that the ozone shield is being depleted well beyond changes due to natural processes.

For over 50 years, chlorofluorocarbons (CFCs) were thought of as miracles. They are stable, nonflammable, low in toxicity, and inexpensive to produce. Over time, CFCs found uses as refrigerants, solvents, foam blowing agents, and in other smaller applications. Other chlorine-containing compounds include methyl chloroform, a solvent, and carbon tetrachloride, an industrial chemical. Halons, extremely effective fire extinguishing agents, and methyl bromide, an effective produce and soil fumigant, contain bromine. All of these compounds have atmospheric lifetimes long enough to allow them to be transported by winds into the stratosphere. Because they release chlorine or bromine when they break down, they damage the protective ozone layer. The discussion of the ozone depletion process below focuses on CFCs, but the basic concepts apply to all of the ozone-depleting substances (ODS).

In the early 1970s, researchers began to investigate the effects of various chemicals on the ozone layer, particularly CFCs, which contain chlorine. They also examined the potential impacts of other chlorine sources. Chlorine from swimming pools, industrial plants, sea salt, and volcanoes does not reach the stratosphere. Chlorine compounds from these sources readily combine with water and repeated measurements show that they rain out of the troposphere very quickly. In contrast, CFCs are very stable and do not dissolve in rain. Thus, there are no natural processes that remove the CFCs from the lower atmosphere. Over time, winds drive the CFCs into the stratosphere. The CFCs are so stable that only exposure to strong UV radiation breaks them down. When that happens, the CFC molecule releases atomic chlorine. One chlorine atom can destroy over 100,000 ozone molecules. The net effect is to destroy ozone faster than it is naturally created.

Large volcanic eruptions can have an indirect effect on ozone levels. Although Mt. Pinatubo's 1991 eruption did not increase stratospheric chlorine concentrations, it did produce large amounts of tiny particles called aerosols (different from consumer products also known as aerosols). These aerosols increase chlorine's effectiveness at destroying ozone. The aerosols only increased depletion because of the presence of CFC- based chlorine. In effect, the aerosols increased the efficiency of the CFC siphon, lowering ozone levels even more than would have otherwise occurred. Unlike long-term ozone depletion, however, this effect is short-lived. The aerosols from Mt. Pinatubo have already disappeared, but satellite, ground-based, and balloon data still show ozone depletion occurring closer to the historic trend.

One example of ozone depletion is the annual ozone "hole" over Antarctica that has occurred during the Antarctic Spring since the early 1980s. Rather than being a literal hole through the layer, the ozone hole is a large area of the stratosphere with extremely low amounts of ozone. Ozone levels fall by over 60% during the worst years.

In addition, research has shown that ozone depletion occurs over the latitudes that include North America, Europe, Asia, and much of Africa, Australia, and South America. Over the U.S., ozone levels have fallen 5-10%, depending on the season. Thus, ozone depletion is a global issue and not just a problem at the South Pole.

Reductions in ozone levels will lead to higher levels of UVB reaching the Earth's surface. The sun's output of UVB does not change; rather, less ozone means less protection, and hence more UVB reaches the Earth. Studies have shown that in the Antarctic, the amount of UVB measured at the surface can double during the annual ozone hole. Another study confirmed the relationship between reduced ozone and increased UVB levels in Canada during the past several years.

Laboratory and epidemiological studies demonstrate that UVB causes nonmelanoma skin cancer and plays a major role in malignant melanoma development. In addition, UVB has been linked to cataracts. All sunlight contains some UVB, even with normal ozone levels. It is always important to limit exposure to the sun. However, ozone depletion will increase the amount of UVB, which will then increase the risk of health effects. Furthermore, UVB harms some crops, plastics and other materials, and certain types of marine life.

Since the appearance of an �ozone hole� over the Antarctic in the early 1980s, people have become aware of the health threats posed by ozone depletion, which decreases our atmosphere�s natural protection from the sun�s harmful ultra-violet (UV) rays.

The incidence of skin cancer in the United States has reached epidemic propor-tions. One in five Americans will develop skin cancer in their lifetime, and one American dies every hour from this devastating disease. Medical research is help-ing us understand the causes and effects of skin cancer. Many health and educa-tion groups are working to reduce the incidence of this disease, of which one million cases have been predicted for 1999 alone.

Other UV-related skin disorders include actinic keratoses and premature aging of the skin. Actinic keratoses are skin growths that occur on body areas exposed to the sun. The face, hands, forearms, and the �V� of the neck are especially susceptible to this type of lesion. Although premalignant, actinic keratoses are a risk factor for squamous cell carcinoma. Look for raised, reddish, rough-tex-tured growths and seek prompt medical attention if you discover them. Chronic exposure to the sun also causes premature aging, which over time can make the skin become thick, wrinkled, and leathery. Since it occurs gradually, often mani-festing itself many years after the majority of a person�s sun exposure, premature aging is often regarded as an unavoidable, normal part of growing older. With proper protection from UV radiation, however, most premature aging of the skin can be avoided.

Cataracts are a form of eye damage in which a loss of transparency in the lens of the eye clouds vision. If left untreated, cataracts can lead to blindness. Research has shown that UV radiation increases the likelihood of certain cataracts. Although curable with modern eye surgery, cataracts diminish the eyesight of millions of Americans and cost billions of dollars in medical care each year. Other kinds of eye damage include pterygium (i.e., tissue growth that can block vision), skin cancer around the eyes, and degeneration of the macula (i.e., the part of the retina where visual perception is most acute). All of these problems can be lessened with proper eye protection from UV radiation.

Scientists have found that overexposure to UV radiation may suppress proper functioning of the body�s immune system and the skin�s natural defenses. All people, regardless of skin color, might be vulnerable to effects including impaired response to immunizations, increased sensitivity to sunlight, and reac-tions to certain medications.

What is the ozone layer and why is it important?
The ozone layer is a concentration of ozone molecules in the stratosphere. About 90% of the planet's ozone is in the ozone layer. The layer of the Earth's atmosphere that surrounds us is called the troposphere. The stratosphere, the next higher layer, extends about 10-50 kilometers above the Earth's surface. Stratospheric ozone is a naturally-occurring gas that filters the sun's ultraviolet (UV) radiation. A diminished ozone layer allows more radiation to reach the Earth's surface. For people, overexposure to UV rays can lead to skin cancer, cataracts, and weakened immune systems. Increased UV can also lead to reduced crop yield and disruptions in the marine food chain. UV also has other harmful effects.

How does ozone depletion occur?
It is caused by the release of chlorofluorocarbons (CFCs) and other ozone-depleting substances (ODS), which were used widely as refrigerants, insulating foams, and solvents. The discussion below focuses on CFCs, but is relevant to all ODS. Although CFCs are heavier than air, they are eventually carried into the stratosphere in a process that can take as long as 2 to 5 years. Measurements of CFCs in the stratosphere are made from balloons, aircraft, and satellites.

When CFCs reach the stratosphere, the ultraviolet radiation from the sun causes them to break apart and release chlorine atoms which react with ozone, starting chemical cycles of ozone destruction that deplete the ozone layer. One chlorine atom can break apart more than 100,000 ozone molecules.

Other chemicals that damage the ozone layer include methyl bromide (used as a pesticide), halons (used in fire extinguishers), and methyl chloroform (used as a solvent in industrial processes). As methyl bromide and halons are broken apart, they release bromine atoms, which are 40 times more destructive to ozone molecules than chlorine atoms.

How do we know that natural sources are not responsible for ozone depletion?
While it is true that volcanoes and oceans release large amounts of chlorine, the chlorine from these sources is easily dissolved in water and washes out of the atmosphere in rain. In contrast, CFCs are not broken down in the lower atmosphere and do not dissolve in water. The chlorine in these human-made molecules does reach the stratosphere. Measurements show that the increase in stratospheric chlorine since 1985 matches the amount released from CFCs and other ozone-depleting substances produced and released by human activities.

What is being done about ozone depletion?
In 1978, the use of CFC propellants in spray cans was banned in the U.S. In the 1980s, the Antarctic "ozone hole" appeared and an international science assessment more strongly linked the release of CFCs and ozone depletion. It became evident that a stronger worldwide response was needed. In 1987, the Montreal Protocol was signed and the signatory nations committed themselves to a reduction in the use of CFCs and other ozone-depleting substances.

Since that time, the treaty has been amended to ban CFC production after 1995 in the developed countries, and later in developing. Today, over 160 countries have signed the treaty. Beginning January 1, 1996, only recycled and stockpiled CFCs will be available for use in developed countries like the US. This production phaseout is possible because of efforts to ensure that there will be substitute chemicals and technologies for all CFC uses.

EPA coordinates numerous regulatory programs designed to help the ozone layer and continues to be active in developing international ozone protection policies. Individuals can also help, primarily by ensuring that technicians working on air conditioning and refrigeration equipment are certified by EPA, that refrigerants are recaptured and not released, and by educating themselves about the issue of ozone depletion. A longer article explains EPA's ozone protection efforts in more detail

Is there general agreement among scientists on the science of ozone depletion?
Yes. Under the sponsorship of the UN Environment Programme (UNEP) and the World Meteorological Organization (WMO), the scientific community issues periodic reports. Almost 300 scientists worldwide drafted and reviewed the WMO/UNEP Scientific Assessment of Ozone Depletion: 1994. An international consensus about the causes and effects of ozone depletion has emerged. (Note: an Adobe Acrobat (PDF) version of the Executive Summary of the 1998 Assessment is available from NOAA's web site.)

Will the ozone layer recover? Can we make more ozone to fill in the hole?
The answers, in order, are: yes and no. We can't make enough ozone to replace what's been destroyed, but provided that we stop producing ozone-depleting substances, natural ozone production reactions should return the ozone layer to normal levels by about 2050. It is very important that the world comply with the Montreal Protocol; delays in ending production could result in additional damage and prolong the ozone layer's recovery.